A Dense I 1 O 3 Hybrid Superhydrophobic Network, Pb(H-BTMB), Exhibits Selectivity toward CO 2 Gas Sorption

Dimensions

Rao, Koya Prabhakara and Devi, Yerraguntla Katyayani and Suryachandram, Jettiboina and Rao, Rayavarapu Prasada and Behera, J. N. (2017) A Dense I 1 O 3 Hybrid Superhydrophobic Network, Pb(H-BTMB), Exhibits Selectivity toward CO 2 Gas Sorption. Inorganic Chemistry, 56 (18). pp. 11184-11189. ISSN 0020-1669

Text
55.pdf
Download (2MB)

School: School of Applied Science and Humanities > Department of Chemistry

Department: School of Applied Science and Humanities > Department of Chemistry

Official URL: https://doi.org/10.1021/acs.inorgchem.7b01551

Abstract

We achieved a dense I1 O3 hybrid superhydrophobic
porous coordination polymer (PCP), [Pb(H-BTMB)(DMF)] (1),
by solvothermal methods. The single-crystal XRD structure of 1
indicated that it has a three-dimensional M−L−M framework with one-dimensional M−O−M connectivity leading to an I1
O3 network. The new PCP obtained exhibited open metal sites
(OMSs) by losing a coordinated DMF molecule. The degassed
phase displayed selective adsorption of CO2 gas over N2, C2H6, and C2H4 gases. Additionally, it has a superhydrophobic surface with a contact angle of 156.4° at room temperature and it is stable even at 90 °C, displaying a contact angle of 135.3°.

Item Type:	Article
Subjects:	AC Rearch Cluster
Depositing User:	Unnamed user with email techsupport@mosys.org
Date Deposited:	01 Feb 2024 10:59
Last Modified:	01 Feb 2024 10:59
URI:	https://ir.vignan.ac.in/id/eprint/723

Actions (login required)

: View Item