Solvent-Free Alkylation of 1,3-Dicarbonyl Compounds with Benzylic, Propargylic and Allylic Alcohols Catalyzed by La(NO3)3·6H2O

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Subramanyam, Madala and Rao, Koya Prabhakara and Varala, Ravi and Basaveswara Rao, Mandava V. (2016) Solvent-Free Alkylation of 1,3-Dicarbonyl Compounds with Benzylic, Propargylic and Allylic Alcohols Catalyzed by La(NO3)3·6H2O. Asian Journal of Chemistry, 28 (5). pp. 1155-1160. ISSN 09707077

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School: School of Applied Science and Humanities > Department of Chemistry

Department: School of Applied Science and Humanities > Department of Chemistry

Official URL: https://doi.org/10.14233/ajchem.2016.19621

Abstract

An efficient and solvent free method for benzylation, propargylation and allylation of 1,3-dicarbonyl compounds with alcohols has been developed by using La(NO3)3·6H2O as water tolerable catalyst. The reaction was shown to proceed smoothly for various 1,3-dicarbonyl compounds with benzylic, propargylic and allylic alcohols including 10 allylic alcohols, without any solvent, providing a clean access to the desired products in short reaction times with good to excellent yields and high selectivity

Item Type:	Article
Subjects:	AC Rearch Cluster
Depositing User:	Unnamed user with email techsupport@mosys.org
Date Deposited:	01 Feb 2024 10:56
Last Modified:	01 Feb 2024 10:56
URI:	https://ir.vignan.ac.in/id/eprint/721

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