Morita–Baylis–Hillman (MBH) Reaction Derived Nitroallylic Alcohols, Acetates and Amines as Synthons in Organocatalysis and Heterocycle Synthesis

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Huang, W.-Y and Anwar, S. and Chen, K. (2017) Morita–Baylis–Hillman (MBH) Reaction Derived Nitroallylic Alcohols, Acetates and Amines as Synthons in Organocatalysis and Heterocycle Synthesis. Chemical Record, 17 (3). pp. 363-381. ISSN 1528-0691

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School: School of Applied Science and Humanities > Department of Chemistry

Department: School of Applied Science and Humanities > Department of Chemistry

Abstract

The Morita–Baylis–Hillman (MBH) reaction is one of the most useful and efficient protocols for constructing new carbon–carbon bonds between an activated olefin and electrophiles in the presence of a tertiary amine/phosphine. Herein, we present the use of MBH alcohols, which are obtained from the reaction of nitrostyrenes with aldehydes, as well as acetates and
amines derived thereof in several organocatalytic transformations. Densely functionalised MBH
adducts can also be used to synthesise substituted heteroaromatic compounds, such as furan,
pyrrole, pyrazole and imidazole derivatives

Item Type:	Article
Subjects:	AC Rearch Cluster
Depositing User:	Unnamed user with email techsupport@mosys.org
Date Deposited:	19 Dec 2023 11:58
Last Modified:	19 Dec 2023 11:58
URI:	https://ir.vignan.ac.in/id/eprint/604

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